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Chlorouracil (4-Chlorouracil; 6-Chlorouracil) is a halogenated uracil that is useful in studies of the effects of halogenation on nucleic acid base-pair stability and alkali metal ion affinity. Reaction of 6-chlorouracil with 4-(dimethylamino)pyridine, 4-methylpyridine, and pyridin-4-yl-morpholine yielded pyridinium-substituted uracils as chlorides which were converted into pyridinium.
Nagata N, Tanaka R, Satoh S and Tanaka A (2005) Identifica-tion of a vinyl reductase gene for chlorophyll synthesis in Arabidopsis thaliana and implications for the evolution of Prochlorococcus species. Plant Cell 17: 233-240 PubMed CrossRef Google Scholar. Nakayama M, Masuda T, Bando T, Yamagata H, Ohta H and Takamiya K (1998) Cloning and Expression of the soybean Chlh gene encoding a subunit.
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Synthesis of Chloroform Essay; Synthesis of Chloroform Essay. 2440 Words 10 Pages. Show More. Synthesis of Chloroform-----With Calcium Hypochlorite and Acetone When chlorine is passed into boiling alcohol, both chlorination of the methyl group and oxidation of the primary alcohol group to an aldehyde occur, giving trichloro-acetaldehyde or chloral: When chloral is treated with caustic alkali.
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HIV-2 as well as HIV-1 (5). All of these compounds are 6-substituted uracil derivatives, which are compara- tively difficult to synthesize in large quantities; there-fore, 1,3-disubstituted uracils have been synthesized and examined for their anti-HIV-1 activity (6). The introduction of 3-methylbenzyl group at N3-position of uracil was highly effective in inhibiting HIV-1 rep-lication in vitro.
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Complete schematic view of the 1960 Chlorophyll A's synthesis performed by Robert B. Woodward.
This chapter discusses the synthesis of chlorophyll a. The basic approach to the synthesis involved making suitably substituted porphyrins and then introducing the still-missing substituents along with the two extra hydrogens in positions 7 and 8. Fischer discussed various methods for synthesizing porphyrins. All these reactions involve condensations of two pyrromethene halves under drastic.
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